What does PBAT stand for?
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May. 13, 2024
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Polybutylene adipate terephthalate - Wikipedia
Biodegradable copolymer, chemical compound
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Biodegradable copolymer
PBAT (which stands for polybutylene adipate terephthalate) is a type of biodegradable random copolymer that serves as a copolyester of adipic acid, 1,4-butanediol, and terephthalic acid. Numerous manufacturers produce PBAT under various brand names such as ecoflex, Wango, Ecoworld, Eastar Bio, and Origo-Bi. It is often also referred to as poly(butylene adipate-co-terephthalate), polybutyrate-adipate-terephthalate, or simply "polybutyrate." PBAT is promoted as a biodegradable alternative to low-density polyethylene, celebrated for its flexibility and resilience, making it suitable for similar applications like plastic bags and wraps. Structurally, it consists of random blocks of butanediol–adipic acid and butanediol-terephthalic acid.
History
Global industrial use of plastics represents a massive market, with PET (polyethylene terephthalate) as one of the leading products, extensively used for making lightweight and rigid bottles. Yet, the durability of PET poses an environmental challenge due to its resistance to biodegradation. Given the high production and disposal rate of PET, with only 15%-35% being recycled and most ending up in landfills, researchers have focused on finding polymers similar to PET but biodegradable. The ideal biodegradable plastics should be affordable, renewable, and eco-friendly, while being resistant and flexible. Since no homopolymer meets all these criteria, researchers have explored copolymers like PBAT for their combined properties.
PBAT, known for its remarkable flexibility and toughness, is blended with other biodegradable polymers that are strong but brittle, thus producing durable yet eco-friendly plastics capable of replacing traditional materials in numerous applications.
Properties
Due to its random polymer structure, PBAT cannot significantly crystallize, resulting in notable physical properties. It has a wide melting point range, low elastic modulus and stiffness, yet is highly flexible and tough. This makes PBAT ideal for blending with strong, rigid biodegradable polymers for products like bottles. However, its flexibility means it lacks the rigidity needed for some applications, such as transparent barriers like plexiglass.
Being fully biodegradable in compost environments, PBAT breaks down due to its butylene adipate components while gaining mechanical stability from its terephthalate segments. It’s less effective in degrading in marine and freshwater environments.
Preparation
PBAT synthesis involves polymerizing adipic acid with 1,4-butanediol, and dimethyl terephthalate (DMT) with 1,4-butanediol. The combination produces their respective polyesters plus water or methanol. Using tetrabutoxytitanium (TBOT) as a catalyst, these polyesters are transesterified to create the PBAT random copolymer, resulting in unpredictable chain structuring. The production involves using excess 1,4-butanediol to influence chain lengths.
Commercial Sources
PBAT is produced by companies like BASF under the name ecoflex, often blended with other materials like poly(lactic acid) in Ecovio. Other producers include Novamont's Origo-Bi, Zhuhai Wango Chemical's Wango, and Eastman Chemical’s Eastar Bio, among others. Across different nations, various companies continuously contribute to PBAT production, meeting diverse industry demands.
Current and Future Uses
Commercially, PBAT is marketed as a fully biodegradable plastic achieving notable degradation rates, such as BASF's ecoflex showing 90% degradation in 80 days. It is used in food packaging wraps, compostable garden bags, agricultural films, and coatings for paper cups and other materials. Given its high flexibility, PBAT also enhances the biodegradability of more rigid polymers in composite applications.
Researchers continue exploring PBAT's potential, such as its role in antimicrobial films used in food packaging to prevent bacterial growth, which would add significant value in preserving food products.
References
What is PBAT plastic? Pros and cons of PBAT - EuroPlas
What is PBAT plastic? Pros and cons of PBAT
PBAT, also known as Polybutylene Adipate Terephthalate, is increasingly recognized as a biodegradable and compostable plastic made from renewable resources like corn starch and sugarcane. Its ability to decompose naturally positions PBAT as an eco-friendly alternative, addressing plastic pollution issues. This article delves into PBAT's benefits, drawbacks, and its diverse applications, guiding businesses and consumers in making more sustainable choices.
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For more information, visit is pbat compostable.
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- PLA masterbatch - the future of the plastic industry
1. What is PBAT plastic?
1.1. What is PBAT?
PBAT (Polybutylene Adipate Terephthalate) is a thermoplastic polymer valued for its biodegradability and compostability. Derived from renewable resources such as sugar cane and corn starch, PBAT combines polybutylene adipate and terephthalic acid. Known for reducing ecological footprints, it is extensively used in packaging and consumer goods, promoting sustainable solutions with growing market adoption.
1.2. Applications:
PBAT's impressive flexibility and moisture resistance make it suitable for numerous applications:
- Compostable food packaging: ideal for fruit/vegetable bags and cereal boxes, PBAT’s barrier properties help extend food shelf life.
- Compostable agriculture films: its durability and resistance to moisture enable efficient use in mulch films, greenhouse covers, and silage wraps.
- Compostable biodegradable shopping bags: reduces plastic waste via biodegradable alternatives.
- Compostable home and personal care products: applied in items like shampoo bottles and toothbrushes.
- Medical products: utilized in sutures, wound dressings, and other devices.
PBAT's versatility and eco-friendliness are promising for future expansion as more businesses seek environmentally friendly materials.
2. Advantages and disadvantages of PBAT
2.1. Advantages of PBAT:
- Biodegradability and compostability: Breaks down into constituent parts, minimizing environmental impact.
- Renewable resources: Made from sugar cane and corn starch, reducing dependence on petroleum-based resources.
- Versatile: Suitable for numerous uses due to its flexibility.
- Good barrier properties: Extends packaged goods' shelf life by providing a barrier against gases and liquids.
2.2. Disadvantages of PBAT:
- Cost: More expensive compared to conventional plastics, potentially higher consumer costs.
- Limited industrial use: Less widespread application in various industries can limit availability.
- Environmental impact: Requires specific conditions for effective composting, and improper disposal can still impact ecosystems.
- Performance limitations: Lower melting temperature and decreased UV/heat resistance when compared to traditional plastics.
3. PBAT vs PLA: what is the difference?
PBAT and PLA (Polylactic Acid) are both eco-friendly plastics, yet they differ significantly:
- Composition: PBAT is a copolymer of polybutylene adipate and polyethylene terephthalate; PLA is derived from lactic acid.
- Performance: PBAT is flexible and tough, suitable for food packaging; PLA is stiff and suitable for applications needing structural stability.
- Biodegradability: PBAT degrades faster than PLA.
- Cost: PLA is typically cheaper than PBAT.
Each plastic has advantages depending on the application, performance needs, cost considerations, and environmental impact.
4. Finding a reliable PBAT plastic supplier?
As companies shift towards sustainable alternatives, finding reliable PBAT suppliers is crucial. EuroPlas, a leading Vietnamese masterbatch manufacturer, offers bioproducts like BiONext bio-compound and BiOMates bio filler, catering to various industries' bioplastic needs.
4.1. Bio compound - BiONext
- Components: Combines bioplastic and materials such as CaCO3, starch, plasticizers, talc, and additives.
- Characteristics: Biodegradable within 12 months, offers high stiffness, low melt flow index, and impact strength. Suitable for direct processing.
- Applications: Versatile use in food packaging, shopping bags, and more.
- Product Codes: Available in codes 102, 152, 400, 500, 600, and 700, each with distinct properties.
4.2. Biofiller - BiOMates
- Components: Made from bio-resin, CaCO3, BaSO4, talc, and additives.
- Characteristics: Biodegradable, cost-effective with other bio-resin use.
- Applications: Used in film, dental picks, utensils, packaging, and more.
- Product Codes: Available codes include 01, 02, and 03, tailored for various needs.
These bioproducts underscore EuroPlas's commitment to producing high-quality environmentally-friendly materials. With over 15 years of industry experience, EuroPlas prides itself on top-tier products and outstanding customer service. For those seeking to incorporate biodegradable materials, EuroPlas is a valuable partner. For more information or inquiries, please contact. Embark on a sustainable future with EuroPlas.
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